五氟磺酰基（SF 5）有机分子的合成化学和生物活性,Journal of Fluorine Chemistry
五氟磺酰基（SF 5）是一种高度稳定的化学功能，由于其独特的化学，结构，物理化学和生物学特性而引起了人们的极大兴趣。缺乏将SF 5-基团引入有机分子的简单的实验室规模的合成方法，在某种程度上阻碍了SF 5-化合物领域的进展。但是，最近的综合进展，商业供应商提供了一些SF 5构件以及发现了SF 5有趣的特性。材料科学，生物学和药物发现中的取代分子为这一令人着迷的氟化学领域的研究提供了新的动力。本文对SF 5取代的有机分子的合成，反应性和生物学特性进行了综述，重点是2000年后发表的工作。
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Synthetic chemistry and biological activity of pentafluorosulphanyl (SF5) organic molecules
The pentafluorosulphanyl group (SF5) is a highly stable chemical function which has been attracting a great deal of interest owing to its peculiar chemical, structural, physicochemical and biological properties. Progress in the area of SF5-compounds has been somewhat hindered by the lack of straightforward lab-scale synthetic methods for introducing the SF5-group into organic molecules. However, recent synthetic progress, the availability of some SF5-building blocks from commercial suppliers and the discovery of interesting properties of SF5-substituted molecules in materials science, biology and drug discovery are giving new momentum to research in this fascinating area of fluorine chemistry. Synthesis, reactivity and biological properties of SF5-substituted organic molecules are herein reviewed with an emphasis on the work published after year 2000.